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M A T E R I A L   S A F E T Y   D A T A   S H E E T

Generated  05/18/2010,   Revision  05/18/2010,   Supercedes Revision  02/10/2009,   Date Created  09/20/2006

SECTION 1. Product and Company Identification
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Product Code: 2724-497-270
Product Name: BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES
Manufacturer Information
     Company Name: Distributed by:
  Farnam Companies, Inc.
  301 West Osborn Road
  Phoenix, AZ
     Emergency Contact: CHEMTREC                                (800)424-9300
     Alternate Emergency Contact: District of Columbia                    (202)483-0414
     Information: Farnam Companies, Inc.                  (800)234-2269
Preparer Name: S.Faith, Regulatory
Additional Identity Information
Dogs 16-30 lbs 3006002 (3 X 0.034 fl oz) 3-mo supply
Dogs 16-30 lbs 3006006 (6 X 0.034 fl oz) 6-mo supply
Dogs 31-60 lbs 3006001 (3 X 0.068 fl oz) 3-mo supply
Dogs 31-60 lbs 3006005 (6 X 0.068 fl oz) 6-mo supply
Dogs over 60 lbs 3005979 (3 X 0.101 fl oz) 3-mo supply
Dogs over 60 lbs 3006004 (6 X 0.101 fl oz) 6-mo supply
Dogs under 15 lbs 3006003 (3 X 0.034 fl oz) 3-mo supply
Dogs under 15 lbs 3006007 (6 X 0.034 fl oz) 6-mo supply

SECTION 2. Composition/Information on Ingredients
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Hazardous Components (Chemical Name) CAS # Concentration OSHA PEL ACGIH TLV
2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, 1-methylethyl ester, [S-(E,E)]- 65733-16-6 3.0 % No data. No data.
Permethrin 52645-53-1 45.0 % No data. No data.

SECTION 3. Hazards Identification
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Emergency Overview
CAUTION: KEEP OUT OF REACH OF CHILDREN
Hazards to Humans: Avoid contact with eyes, skin or clothing. Wash thoroughly with saop and water after handling.
Route(s) of Entry: Inhalation? N.A. , Skin? Yes , Eyes? Yes , Ingestion? Yes
Potential Health Effects (Acute and Chronic)
No data available.
Recommended Exposure Limits
Not established.
LD 50 / LC 50
Oral LD50>5.0g/kg; Dermal LD50>5.0g/kg
Signs and Symptoms Of Exposure
May cause minor skin irritation. May cause minor eye irrittation. Not a contact sensitizer.

SECTION 4. First Aid Measures
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Emergency and First Aid Procedures
IF IN EYES: Hold eyes open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes.
IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 -20 minutes. Call poison control center or physician for treatment advice.
IF INGESTED: Call physician. Do not induce vomiting or give anything by mouth if person is unconscious.
IF INHALED: Remove individual to fresh air. If breathing does not return to normal withina few minutes, get medical attention immediately. If breathing is difficult, administer oxygen.
Note to Physician
NA
Additional First Aid Information
Have the product container or label with you when calling a poison control center or doctor or going for treatment.

SECTION 5. Fire Fighting Measures
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Flammability Classification: Combustible
Flash Pt: 131.00 F
Explosive Limits: LEL:  Unknown          UEL:  Unknown
Autoignition Pt: NA
Fire Fighting Instructions
Firefighters should wear full protective clothing including self-contained breathing apparatus.Normal procedures. Do not allow fire fighting water to escape into water-ways or sewers.
Flammable Properties and Hazards
Large Quantities: Vapors may travel along the ground or be moved byVentilation and ignited by heat, pilot lights, other flames and ignition sourcesat locations distant from material handling point. Never use welding or cutting torch near product. Product may ignite easily.
Hazardous Combustion Products
Carbon dioxide and carbon monoxide
Extinguishing Media
Water, CO2 dry chemicals, foam
Unsuitable Extinguishing Media
None known

SECTION 6. Accidental Release Measures
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Steps To Be Taken In Case Material Is Released Or Spilled
Do not allow spill to enter water ways inhabited by aquatic organisms. Soak up with absorbent material and place in a suitable container for disposal. Absorbents: Clay granules, dirt, or equivalent.

SECTION 7. Handling and Storage
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Precautions To Be Taken in Handling
Avoid eye contact. Wash hands after handling.
Precautions To Be Taken in Storing
Do not contaminate water, food, or feed by storage. Store in a dry, cool place out of the reach of children and pets.

SECTION 8. Exposure Controls/Personal Protection
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Respiratory Equipment (Specify Type)
See below.
Eye Protection
See below.
Protective Gloves
See below.
Other Protective Clothing
Not needed if product is used according to label. If prolonged exposure is anticipated, wear impervious gloves and safety glasses or goggles.
Engineering Controls (Ventilation etc.)
General ventilation is sufficient.
Work/Hygienic/Maintenance Practices
Wash hands with soap and water after handling and before eating, drinking, smoking or using the restroom.

SECTION 9. Physical and Chemical Properties
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Physical States: [   ] Gas       [ X ] Liquid       [   ] Solid
Melting Point: NA
Boiling Point: 392.00 F
Autoignition Pt: NA
Flash Pt: 131.00 F
Explosive Limits: LEL:  Unknown          UEL:  Unknown
Specific Gravity (Water = 1): 1.03
Density: 8.612 LB/GA
Bulk density:                        NA
Vapor Pressure (vs. Air or mm Hg):                        NA
Vapor Density (vs. Air = 1): >1
Evaporation Rate (vs Butyl Acetate=1):                        NA
Solubility in Water: Insoluble
Percent Volatile: N.A.
Saturated Vapor Concentration:                        NA
Viscosity:                        NA
Heat Value:                        NA
Particle Size:                        NA
Corrosion Rate:                        NA
pH:                        NA
Appearance and Odor
Light amber liquid.

SECTION 10. Stability and Reactivity
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Stability: Unstable [    ]       Stable [ X ]
Conditions To Avoid - Instability
No data available.
Incompatibility - Materials To Avoid
Avoid contact with strong oxidizing agents.
Hazardous Decomposition Or Byproducts
Not determined.
Hazardous Polymerization: Will occur [    ]       Will not occur [ X ]
Conditions To Avoid - Hazardous Polymerization
No data available.

SECTION 11. Toxicological Information
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

CHRONIC TOXICITY[Based on (RS)-Methoprene Technical]
Methoprene is not considered a carcinogenic compound. Permethrin is not considered a carcinogenic compound.
DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Based on (RS)-Methoprene Technical ]
Methoprene is not a teratogenic compound. Permethrin is not a teratogenic compound.
MUTAGENICITY [Based on (S)-Methoprene Technical]
Methoprene is not a mutagenic compound. Permethrin is not a mutagenic compound.
Carcinogenicity/Other Information
No data available.
Hazardous Components (Chemical Name) CAS # NTP IARC ACGIH OSHA
2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, 1-methylethyl ester, [S-(E,E)]- 65733-16-6 n.a. n.a. n.a. n.a.
Permethrin 52645-53-1 n.a. n.a. n.a. n.a.
Carcinogenicity: NTP? No       IARC Monographs? No       OSHA Regulated? No

SECTION 12. Ecological Information
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

ENVIRONMENTAL FATE
(RS) Methoprene Technical Permethrin
Hydrolysis: T1/2 > 4 weeks ~ 20 days
Photolysis: T1/2 < 10 hours ~ 10 hours
Soil half life: ~ 10 days ~ 4 Weeks
Water solubility: < 2 ppm ~ 0.04 ppm

Acute Toxicity: Th is product is toxic to fish.(S) Methoprene Technical: LC50 (trout): 760ppb, (Bluegill): >370ppb; aquatic invertebrates: LC50 (Daphnia): 360 ppbPermethrin Technical: 1.4 to 7.9 mg/1L (trout)

SECTION 13. Disposal Considerations
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Waste Disposal Method
If Empty: Do not reuse empty applicator. Place in trash and offer for recycling if available.
If Partly Filled: Call your local solid waste agency. Never place unused product down any indoor or outdoor drain.

SECTION 14. Transport Information
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

LAND TRANSPORT (US DOT)
     DOT Proper Shipping Name Not regulated as hazardous by U.S. DOT
     DOT Hazard Label: None

SECTION 15. Regulatory Information
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

No data available.

SECTION 16. Other Information
BIO SPOT SPOT ON FLEA & TICK CONTROL FOR DOGS & PUPPIES

Company Policy or Disclaimer
The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable.  It is offered for your consideration, investigation and verification.
Flammability
Health
1
2 b
Instability
Special Hazard
Minimal:0
Slight:1
Moderate:2
Serious:3
Extreme:4
Generated  05/18/2010
Revision  05/18/2010
Supercedes Revision  02/10/2009
Date Created  09/20/2006