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SECTION 1. Product and Company Identification
Adams Plus Flea & Tick Collar for Dogs

Product Code: 2724-493-270
Product Name: Adams Plus Flea & Tick Collar for Dogs
Manufacturer Name and Address:Telephone Numbers:Dates:
Distributed by:CHEMTREC(800)424-9300Date Created: 12/20/2006
Farnam Companies, Inc.District of Columbia(202)483-0414Revision: 05/04/2007
301 West Osborn RoadFarnam Companies, In(800)234-2269Printed: 05/04/2007
Phoenix, AZ.
Responsible Person: SFaith/Regulatory , Phone #:
Additional Identity Information
Small Dogs: 3006024
Large Dogs: 3006025

SECTION 2. Composition/Information on Ingredients
Adams Plus Flea & Tick Collar for Dogs

  Hazardous Components (Chemical Name)  CAS #   Concentration
1. Propoxur {Phenol,2-(1-methylethoxy)-,methylcarbamate;
Baygon} 		114-26-1 10.0 %
2. 2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, 1-
methylethyl ester, [S-(E,E)]- 		65733-16-6 2.1 %
   OSHA PEL ACGIH TLV
1.   No data.   0.5 mg/m3  
2.   No data.   No data.  

SECTION 3. Hazards Identification
Adams Plus Flea & Tick Collar for Dogs

Emergency Overview
CAUTION: Do not allow children to play with this collar. Do not open protective pouch until ready to use. Dust will form on this collar during storage. Do not get dust of collar in mouth; harmful if swallowed. Do not get in eyes; will cause temporary pupillary constriction. The dust released by this collar is a cholinesterase inhibitor. Wash hands thoroughly with soap and water after handling.
SKIN IRRITATION: Minimally irritating.
EYE IRRITATION: Mildly irritating.
SENSITIZER: Not a sensitizer.
Route(s) of Entry: Inhalation? N.A. , Skin? Yes , Eyes? Yes , Ingestion? N.A.
Potential Health Effects (Acute and Chronic)
No data available.
Carcinogenicity: NTP? N.A. , IARC Monographs? N.A. , OSHA Regulated? N.A.
Carcinogenicity/Other Information
No data available.
Signs and Symptoms Of Exposure
Due to product form, method of use, and use history, human intoxication has not been reported. However, propoxur is a cholinesterase inhibitor that may produce the following symptoms: headache, nausea, vomiting, diarrhea, tightness in chest, ataxia, anorexia, tearing, sweating, salivation, pin-point pupils, pulmonary edema, cyanosis, convulsions.
Medical Conditions Generally Aggravated By Exposure
No data available.

SECTION 4. First Aid Measures
Adams Plus Flea & Tick Collar for Dogs

Emergency and First Aid Procedures
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eyes.
IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
IF INGESTED: Call a poison control center or a doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by poison control center or doctor. Do not give anything by mouth to an unconscious person.
IF INHALED: Remove victim to fresh air.
Note to Physician
Atropine is antidotal only if symptoms of cholinesterase inhibition are present.

SECTION 5. Fire Fighting Measures
Adams Plus Flea & Tick Collar for Dogs

Flash Pt: NA Method Used: No data.
Explosive Limits: LEL: No data. UEL: No data.
Extinguishing Media
Water fog, foam, CO2.
Fire Fighting Instructions
Normal procedures. Do not allow fire fighting water to escape into water-ways or sewers. Firefighters should wear full protective clothing including self-contained breathing apparatus.
Flammable Properties and Hazards
None known.
Hazardous Combustion Products
Highly irritating methyl isocyanate gas and fumes of hydrogen chloride can be formed during burning.

SECTION 6. Accidental Release Measures
Adams Plus Flea & Tick Collar for Dogs

Steps To Be Taken In Case Material Is Released Or Spilled
Because of individual packaging, possibilities of a release or spill are remote. However, should one occur, place in container for proper disposal. Do not allow large quantities to enter waterways. If in liquid form, use clay granules, sawdust, dirt, or equivalent.

SECTION 7. Handling and Storage
Adams Plus Flea & Tick Collar for Dogs

Precautions To Be Taken in Handling
Wash hands and face thoroughly with soap and water after handling product. Do not allow children to handle collar.
Precautions To Be Taken in Storing
Store in original unopened container away from children. Do not open protective pouch until ready to use.
Other Precautions
No data available.

SECTION 8. Exposure Controls/Personal Protection
Adams Plus Flea & Tick Collar for Dogs

Respiratory Equipment (Specify Type)
If extensive exposure is anticipated, users and handlers should wear a NIOSH approved organic vapor/dust/pesticide respirator.
Eye Protection
No data available.
Protective Gloves
No data available.
Other Protective Clothing
If extensive exposure is anticipated, users and handlers should wear impervious gloves, goggles, and other appropriate clothing to prevent skin contact.
Engineering Controls (Ventilation etc.)
Natural ventilation is sufficient.
Additional Exposure Control Information
Not established except for Propoxur: 0.5 mg/m3 (OSHA PEL & ACGIH TLV)

SECTION 9. Physical and Chemical Properties
Adams Plus Flea & Tick Collar for Dogs

Solubility Notes
Slightly soluble in water.
Physical States:  [ ] Gas , [ ] Liquid , [ X ] Solid
Boiling Point: NA
Melting Point:  90.00 C
Specific Gravity (Water = 1): No data.
Density: NA
Vapor Pressure (vs. Air or mm Hg): 1.29 mPa at 20.0 C
Vapor Density (vs. Air = 1): No data.
Evaporation Rate (vs Butyl Acetate=1):  NA
Solubility in Water: 0.2% at 20.0 C
Percent Volatile: No data.
Saturated Vapor Concentration: No data.
Viscosity: No data.
pH:  NA
Appearance and Odor
Plastic strips with powdery surface, faint phenolic odor.


SECTION 10. Stability and Reactivity
Adams Plus Flea & Tick Collar for Dogs

Stability: Unstable [ ] Stable [ X ]
Conditions To Avoid - Instability
No data available.
Incompatibility - Materials To Avoid
Strong acids, strong oxidizers.
Hazardous Decomposition Or Byproducts
Methyl isocyanate gas, toxic fumes of C1, oxides of nitrogen can be formed on burning.
Hazardous Polymerization: Will occur [ ] Will not occur [ X ]
Conditions To Avoid - Hazardous Polymerization
No data available.

SECTION 11. Toxicological Information
Adams Plus Flea & Tick Collar for Dogs

ACUTE TOXICITY:
Oral: LD50 (rat): >68 mg/kg (Propoxur)
Dermal: LD50 (rabbit): >2.000 mg/kg (Propoxur)
Inhalation: LC50 (rat): 0.5 mg/L (4-hour study) (Propoxur)
Chronic Toxicological Effects
[Specific to Active Ingredient(s)]
In a combined chronic/carcinogenicity toxicity study, rats were fed doses at a maximum 5,000 ppm (222-292 mg/kg/day) for up to 2 years. The NOEL was 200 ppm (8.2 mg/kg/day for males and 11.0 mg/kg/day for females) based on reduced weight gain and urinary bladder hyperplasia.



Additional Toxicological Information
DEVELOPMENTAL/REPRODUCTIVE TOXICITY [Specific to Active Ingredient(s)]
In a developmental toxicity study in rabbits, animals were orally dosed at concentrations up to 30 mg/kg/day. The NOEL for maternal and developmental toxicity was 10 mg/kg/day based on fetal body weight
MUTAGENICITY [Specific to Active Ingredient(s)]
The weight of evidence suggests that Propoxur is not a mutagen.

SECTION 12. Ecological Information
Adams Plus Flea & Tick Collar for Dogs

Acute Toxicity: fish:LC50 (bluegill): 4.8 ppm (96 hour study), (trout): 3.55 ppm (96 hour study); aquatic invertebrates: Daphina: very highly toxic.
Propoxur is highly toxic to honey bees.


SECTION 13. Disposal Considerations
Adams Plus Flea & Tick Collar for Dogs

Waste Disposal Method
Do not reuse container or used collar. Do not contaminate water, feed or food by disposal. If household waste, wrap and put in trash. For larger quantities: dispose of at a state/EPA approved hazardous waste facility.

SECTION 14. Transport Information
Adams Plus Flea & Tick Collar for Dogs

DOT Proper Shipping Name
Not regulated as hazardous by D.O.T.

Additional Transport Information
Freight Classification: Collars, animal insect repellent, in individual retail containers in boxes: NMFC 49998 Sub 1 Class 100. In individual paper and foil laminated pouches other than individual retail containers, in boxes: NMFC 49998 Sub 2 Class 85

SECTION 15. Regulatory Information
Adams Plus Flea & Tick Collar for Dogs

No data available.

SECTION 16. Other Information
Adams Plus Flea & Tick Collar for Dogs

Supercedes Revision 12/20/2006

NFPA Hazard Ratings:
Flammability
Health
b
2 b
Instability
Special Hazard
Minimal:0
Slight:1
Moderate:2
Serious:3
Extreme:4
The information and data herein are believed to be accurate and have been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification.